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 There are two methods by which you can block websites on chrome:- 

1. Use an Extension

You can use the " Blocksite " extension to block the websites. Simply you have to install the extension then enable it. This tool will disable websites on chrome. 

2. Use Google Admin Account:-

For this, you have to log in your administrator account and open chrome. Find search for devices option. Go to chrome then settings. Double click on settings and click on Users and browsers. Find section name URL Blocking . Tap again and paste the URLs you want to block. Save Changes and enjoy. 

To know more, you can visit the link.

https://getassist.net/how-to-block-websites-on-chrome/